I assumed the DVD would be the actual episode that the figures were from.
That was the plan for the Walmart DVD 2-packs, but I don't think it's the case with these.
Like McMetal said, I think the DVD is the same in both sets and I think it's more of a "clip show" DVD. The yellow starburst on the front of both boxes is the same - "Includes Bounty Hunter DVD! Featuring the most notorious Bounty Hunters in the Galaxy!"
Here's a back of the box pic from the RS forums: