Grabbed some of these from one of my posts over in the Hey Hasbro forum and revised a couple of others:
Obi-Wan Kenobi - All super articulate w/ softgoods
-Jedi Padawan - The Phantom Menace
-Jedi Knight - Attack Of The Clones w / headset, tracking device & binoculars
-Jedi Master - A New Hope w/ training remote, lightsaber
Palpatine - SA w/ softgoods
-Senator Palpatine - TPM & black Sidious robe
-Chancellor Palpatine - ROTS duel with Mace Windu w/ changeable heads, lightsaber & force lightning
-Emporer Palpatine - ROTJ - with cane, force lightning
Jedi Masters - All SA w/ softgoods
-Eeth Koth - TPM
-Cin Drallig - Jedi Swordmaster - ROTS
-Yoda - TESB
-Garven Dreis - Red Leader - ANH
-Wedge Antilles - Rogue 2 - TESB (Snowspeeder Pilot gear)
-Arvel Crynyd - Green Leader - ROTJ
DARK SIDE APPRENTICES/ADEPTS
-Aurra Sing - The Phantom Menace - Aurra Sing's got a lot of backstory, so why not make her SA along with her rifle, pistol(s), lightsaber and her case of lightsaber hilts?
-Asajj Ventress - An SA Ventress w/ softgoods & full cloak
-Lumiya - NJO
-A New Hope - Luke in his Tatooine garb, beginning his Jedi training? Make him SA and toss in the blastshield helmet, training remote and lightsaber.
-The Empire Strikes Back - Luke in Snowspeeder Pilot - SA w/ removable helmet, lightsaber, grappling hook & mine
-Return Of The Jedi - This is the perfect vehicle for a Death Star 2 Luke. 'Nuff said.