There are definitely some good options for the Evolutions line. Here are some I've thought of...
Obi-Wan Kenobi
-The Phantom Menace w/ SA, softgoods, rebreather, Obi-Wan's lightsaber, Qui-Gon's lightsaber & CommLink
-Revenge Of The Sith w/ SA, softgoods, lightsaber
-The Empire Strikes Back - Hoth Vision
Luke Skywalker
-A New Hope SA w/ lightsaber, Stormtrooper utility belt, grappling hook, Stormtrooper blaster
-The Empire Strikes Back in Snowspeeder Pilot gear, SA w/ removable helmet, blaster, holster, grappling line, lightsaber & mine
-Return Of The Jedi SA Throne Room duel w/ binders & lightsaber
Han Solo
-A New Hope SA w/ regular blaster & holster, Stormtrooper blaster & holster and medal
-The Empire Strikes Back SA, Carbon Freeze Chamber Han w/ Carbonite block, binders, SG jacket
-Return Of The Jedi - SA Endor battle Han w/ SG trenchcoat, mines
Jedi Masters
-The Phantom Menace Qui-Gon Jinn w/ SA, sg, lightsaber, commlink, holoprojector
-A New Hope Obi-Wan Kenobi w/ SA, sg, lightsaber & training remote
-The Empire Strikes Back Yoda w/ SA, sg, backpack, pot, gimer stick, light
The Fetts
-Attack Of The Clones Jango Fett w/ SA, removable helmet, blaster pistols, both rocketpacks
-Attack Of The Clones Mess Hall Clone Trooper in red fatigues
-Return Of The Jedi Boba Fett w/ SA, sg, rifle
Bounty Hunters
-Zam Wessel w/ SA, sg, two different heads, blaster pistols, rifle
-Greedo w/ SA, blaster pistol
-Zuckuss w/ SA, sg, blaster rifle
Astro Droids
-R2-D2 w/ various tool arms, extendable third leg
-R4-P17 (ROTS) w/ repair tools, removable dome
-R5-D4 w/ extendable third leg, motivator