The Evolutions sets are the best things to ever come out of Hasbro.
My wants...
Luke Skywalker
* Luke (stormtrooper)
* Luke (Bespin, SA)
* Luke (final duel)
Accessories: Stormie helmet, stormie blaster, ANH-ESB lightsaber & hilt, manacles, ROTJ lightsaber & hilt, Endor helmet, Endor poncho, softgoods vest, interchangeable hands (gloved and bare)
Han Solo
* Han (Stormtrooper)
* Han (Bespin, SA)
* Han (Endor)
Accessories: Stormie helmet, stormie blaster, Han's blaster, rebreather, Endor trenchcoat, detonators
Princess Leia
* Leia (celebration)
* Leia (Hoth)
* Leia (General)
Accessories: Alternate head (one Hoth and one Bespin), medals, Endor poncho, Endor Helmet, softgoods Hoth vest, Stormie blaster, hold-out blaster
Stormtrooper (no brainer)
* ANH Stormie (VOTC version is fine)
* Cold weather stormtrooper (snowtrooper, SA, softgoods)
* Scout trooper (SA)
Accessories: 3 stormie rifles, long stormie rifle, scout trooper blaster, snowtrooper backpack, sandtrooper pauldron, sandtrooper backpack
Obi-Wan Kenobi
* Obi-Wan (TPM, SA, softgoods)
* Obi-Wan (AOTC, SA, softgoods)
* Obi-Wan (ROTS, pilot sculpt, with softgoods)
Accessories: rebreather, lightsabers & hilts all around, commlink, pilot headgear, softgoods robes (3), baby Luke and baby Leia
Padme Amidala
* Padme (final battle, SA, softgoods)
* Padme (Geonosis, SA)
* Padme (Leia buns, softgoods)
Accessories: Silver blaster, Acsension-gun blaster, battledroid blaster, softgoods cape, arena chains
Bounty Hunters
* Aurra Sing (or more preferably Zam Wessel, SA)
* Jango Fett (SA)
* Zuckuss (SA, softgoods)
Accessories: Fett's jetpacks (both of them, with removeable rocket), blasters all around, Zam's assassin droid (if Zam is in the set), alternate head for Zam (can you tell I want a new Zam figure?)
Jedi Masters
* Qui-Gon Jinn (SA, softgoods)
* Mace Windu (SA, softgoods)
* Yoda (SA, softgoods)
Accessories: Qui Gon's lightsaber & hilt, Mace Windu's lightsaber & hilt, commlink, rebreather, Yoda's walking stick, Yoda's lightsaber & hilt, alternate hand for Yoda (absorbing force lightning), Yoda's floating chair (with alternate lower half of Yoda, where he's sitting cross-legged)
I really hope Hasbro continues the Evolution line. There's so many possibilities.