Lets update the list with the list posted at GH.com
My most anticipated would be Wat Tambor

Collection 1 Basic Figures 84851
Wave 5 (February)
84870 Obi Wan Spear Throwing
84918 Mace Windu (Total Control)
84919 Darth Tyranus (Lightning Burst)
84927 Anakin Skywalker (Mechanical Arm and Super Arm Articulation)
84920 Classic Boba Fett (Quick Draw)
84922 Flying R2-D2
Wave 6 (May)
84959 Han Solo (Hoth)
84960 Chewbacca (Mynock Hunt)
84977 Luke Skywalker (ROTJ)
84978 Darth Vader (ROTJ)
84979 Snowtrooper (ESB)
Wave 7 (August)
Jango Fett (Clone Wars)
Clone Trooper (Clone Wars)
Yoda (Clone Wars)
Obi-Wan Kenobi (Clone Wars)
Mace Windu (Clone Wars)
Wave 8 (October)
Anakin Skywalker (Clone Wars)
Count Dooku (Clone Wars)
Kit Fisto (Clone Wars)
Collection 2 Basic Figures 84861
Wave 10 (2002) January '03
84993 Rebel Trooper (New Head Sculpt)
84994 Imperial Officer (New head Sculpt)
84995 Eeth Koth
84996 Teebo
Wave 2 (February)
84923 Padme Amidala (with soft cloak and articulation)
84924 SP4 and JN66 (Library Droid 2 Pack)
84921 Tusken Raider with Removable Head
84925 Lama Su and Clone Boy
84928 Twilek Jedi with super articulation
84926 Barriss Offee
Wave 3 (June)
84969 Yoda with Padawan Jedi (2-pack)
84970 Alien Padawan Jedi 2 Pack (Shakti and Shape Shifter)
84989 Padme in Wedding Dress
84990 Wat Tambor *
84991 Coleman Trebor *
Wave 4 (October)
Waitress Droid *
Faytonni Cantina Alien *
2nd Cantina Alien *
Darth Sidious
Bail Organa
Fan's Choice #4 McQuarrie Stormtrooper