Cool, I might have to try the Ash jedi

I think you'll find that Citadel Paints will not chip as much as Apple Barrel. The paints go on
a lot smoother - you
will notice a difference! They do not chip nearly as much as the Apple Barrel/FolkArt/etc paints (especially if you prime the figure). Of course, I think everybody should use Citadel Paints

, but I really can't say enough good stuff about them. Try out one color and you'll see the difference.
I've also heard that Tamiya makes some good paint, although I have yet to try that stuff out.
Chipping aggravates the hell out of me, so another thing that I've found is to gently cut or sand the joint so that there is less brushing between the joints. Sometimes this doesn't work as you can't sand/cut it enough, although it might help with some joints.